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There are two answers:
1. Fill the 3 liter, and pour into the 5.  Fill the 3 liter again, and pour into the 5 liter till it is full, this will give you 1 left in the 3 liter.  Pour out the 5 liter, and pour the remainder from the 3 liter into the 5 liter.  Fill the 3 liter, and pour into the 5 liter, which will give you 1+3 liters (4). 

2. Fill the 5 liter, and pour into the 3 liter till it is full.  Empty the 3 liter.  Take the 2 remaining liters in the 5 liter, and pour into the 3 liter.  Fill the 5 liter again, and pour into the 3 liter till it is full (1 liter), the remainder of the 5 liter will be 4 liters.

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Wednesday, November 07, 2007
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